Synthesis of bottlebrush polymers via transfer-to and grafting-through approaches using a RAFT chain transfer agent with a ROMP-active Z-group
نویسندگان
چکیده
منابع مشابه
Synthesis of bottlebrush polymers via transfer-to and grafting-through approaches using a RAFT chain transfer agent with a ROMP-active Z-group†
A novel dithiocarbamate chain transfer agent (CTA1) with a directly polymerizable Z-group was synthesized for use in reversible addition–fragmentation chain transfer polymerization (RAFT). This CTA effectively mediated RAFT polymerization of styrenic and acrylic monomers with dispersities (Đ) < 1.08. Utilizing the polymerizable Z-group on the ω-chain end that is inherited from the RAFT process,...
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Bottlebrush polymers are highly branched macromolecules with potential applications in antifouling coatings, rheological modifiers, and drug delivery systems. However, the solution conformation of bottlebrush polymers has been studied in only a limited set of materials made primarily by grafting-from polymerization. Here we present small-angle neutron scattering (SANS) measurements on a series ...
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ژورنال
عنوان ژورنال: Polymer Chemistry
سال: 2015
ISSN: 1759-9954,1759-9962
DOI: 10.1039/c4py01567c